Stanislaw Dzwigaj

Domaine d’expertise

Fonctionnalisation de matériaux poreux par des éléments de transition pour applications en catalyse

Curriculum Vitae du Pr. Stanislaw DZWIGAJ

 Les objectifs de recherches 

1. Préparer et étudier des matériaux redox modèles en suivant in situ la cinétique et la sélectivité de dépôt de ces éléments de transition dans des zéolithes,
2. Fonctionnaliser des matériaux poreux acide par la méthode post-synthèse en deux étapes en introduisant différent métaux de transition en position réseau pour obtenir des catalyseurs bifonctionnels,
3. Appliquer des matériaux poreux fonctionnalisés par des éléments de transition dans des réactions importantes du point de vue industriel et environnemental : oxydation déshydrogénante du propane, époxydation du propylène, oxydation de CO, oxydation sélective du méthanol, oxydation partielle de méthane, réaction Fischer-Tropsch, élimination des composés organiques (COV) et NO.  

 

Techniques principales utilisées

XRD, IR, DR UV-vis, TPR, RPE, RMN, XPS

Fonction et rattachement

Chargé de Recherche / CNRS

Carrière

1978 : LRS

***

• Doctorat 1982, Institute de Catalyse à Krakow, Pologne
• Post-doc 1987-1989, LRS
• Habilitation de dirigé de recherche 2004, Institute de Catalyse à Krakow, Pologne
• CNRS Senior Scientiste, 2008-présent
• Professeur de science chimique, 2014 Institute de Catalyse à Krakow, Pologne

Publications

Publications Significatives

1) Anpo, M.; Dzwigaj, S.; Che, M. Applications of photoluminescence spectroscopy to the investigation of oxide-containing catalysts in the working state (Monograph) Advances in Catalysis 52 (2009) 1.

2) Pietrzyk, P.; Sojka, Z.; Dzwigaj, S.; Che, M. Generation, Identification, and Reactivity of Paramagnetic VO2 Centers in Zeolite BEA for Model Studies of Processes Involving Spin Pairing, Electron Transfer, and Oxygen Transfer Journal of the American Chemical Society 129 (2007) 14174.

3) Trejda, M.; Ziolek, M.; Millot, Y.; Chalupka, K.; Che, M.; Dzwigaj, S. Methanol oxidation on VSiBEA zeolites: Influence of V content on the catalytic properties Journal of Catalysis 281 (2011) 169.

4) Janas, J.; Gurgul, J.; Socha, R.P.; Shishido, T.; Che, M.; Dzwigaj, S. Selective catalytic reduction of NO by ethanol: Speciation of iron and "structure-properties" relationship in FeSiBEA zeolite Applied Catalysis, B: Environmental 91 (2009) 113.

5) Ethanol conversion into 1,3-Butadiene by Lebedev method over MTaSiBEA zeolites (M = Ag, Cu, Zn) P. Kyriienko, O. Larina, S. Soloviev, S. Orlyk, C. Calers, S. Dzwigaj ACS Sustainable Chemistry & Engineering, 2017, 5, 2075.

Publications récentes

• Effect of dealumination on the catalytic performance of Cr-containing Beta zeolite in carbon dioxide assisted propane dehydrogenation

P. MICHORCZYK, K. ZENCZAK-TOMERA, B. MICHORCZYK, A. WEGRZYNIAK, M. BASTA, Y. MILLOT, L. VALENTIN, S. DZWIGAJ

J. CO₂ Utilization 2020, 36, 54-63. DOI:10.1016/j.jcou.2019.09.018

• Effect of the Composition of Ethanol-​Water Mixtures on the Properties of Oxide (Zn-​Zr-​Si) and Zeolitic (Ta​/SiBEA) Catalysts in the Production of 1,​3-​Butadiene      

P.I. KYRIIENKO, O.V. LARINA, S. DZWIGAJ, S.O. SOLOVIEV, S.M. ORLYK

Theor. Exper. Chem. 2019, 55, 266-273. DOI:10.1007/s11237-019-09618-1

• Cobalt based catalysts supported on two kinds of beta zeolite for application in Fischer-​Tropsch Synthesis

R. SADEK, K. A. CHALUPKA, P. MIERCZYNSKI, J. RYNKOWSKI, J. GURGUL, S. DZWIGAJ

Catalysts 2019, 9, 497. DOI: 10.1016/j.cattod.2019.05.004

• Fischer-​Tropsch reaction on Co-​containing microporous and mesoporous Beta zeolite catalysts: the effect of porous size and acidity

R. SADEK, K. A. CHALUPKA, P. MIERCZYNSKI, J. RYNKOWSKI, Y. MILLOT, L. VALENTIN, S. CASALE, S. DZWIGAJ

Catal. Today 2019, 354, 109-122. DOI:10.1016/j.cattod.2019.05.004

• Preparation of two series of VxSiBeta zeolite catalysts with V centres in framework and extra-​framework positions and their application in selective oxidation of methanol

M. TREJDA, Y. MILLOT, K. CHALUPKA, S. DZWIGAJ

Appl. Catal. A 2019, 579, 1-8. DOI:10.1016/j.apcata.2019.04.009

• Experimental Evidence of the Mechanism of Selective Catalytic Reduction of NO with NH₃ over Fe-​Containing BEA Zeolites

P. BORON, M. RUTKOWSKA, B. GIL, B. MARSZALEK, L. CHMIELARZ, S. DZWIGAJ

ChemSusChem 2019, 12, 692-705. DOI:10.1002/cssc.201801883

• Design of Bifunctional Catalysts Based on Bea Zeolites for Tandem Processes with Participation of Ethanol

 N.O. POPOVYCH, O.V. LARINA, S.M. ORLYK, P. I. KYRIIENKO, S.O. SOLOVIEV, S. DZWIGAJ

Theoret. Exper. Chem. 2018, 54, 255-264. DOI:10.1007/s11237-018-9571-9

• Low Temperature NOx Adsorption Study on Pd-​Promoted Zeolites

A. PORTA, T. PELLEGRINELLI, L. CASTOLDI, R. MATARRESE, S. MORANDI, S. DZWIGAJ, L. LIETTI

Top. Catal.  2018, 61, 2021-2034. DOI:10.1007/s11244-018-1045-8

• Influence of the Preparation Procedure of Vanadium-​Containing SiBEA Zeolites on Their Catalytic Activity in Propene Epoxidation

A. HELD, J. KOWALSKA-KUS, Y. MILLOT, F. AVERSENG, C. CALERS, L. VALENTIN, S. DZWIGAJ

J.  Phys. Chem. C 2018, 122, 18570-18582. DOI:10.1021/acs.jpcc.8b05731

• Effects of dealumination on the performance of Ni-​containing BEA catalysts in bioethanol steam reforming

W. GAC, M. GRELUK, G. SLOWIK, Y. MILLOT, L. VALENTIN, S. DZWIGAJ

Appl. Catal. B 2018, 237, 94-109. DOI:10.1016/j.apcatb.2018.05.040

• Sn-BEA zeolites prepared by two-step postsynthesis method: Physicochemical properties and catalytic activity in processes based on MPV reduction

N. POPOVICH, P. KYRIIENKO, Y. MILLOT, L. VELENTIN, J. GURGUL, R. SOCHA, J. ZUKROWSKI, S. SOLOVIEV, S. DZWIGAJ

Micropor. Mesopor. Mater. 2018, 268, 178-188. DOI:10.1016/j.micromeso.2018.04.026

• Influence of pretreatment and reactions on the catalytic activity of HAlBEA and CoHAlBEA zeolites in vinyl chloride formation from 1,2-dichloroethane

KAMINSKA, D. LISOVYTSKIY, L. VALENTIN, C. CALERS, Y. MILLOT, E. KOWALEWSKI, A. SREBOWATA, S. DZWIGAJ             

Micropor. Mesopor. Mater. 2018, 266, 32-42. DOI:10.1016/j.micromeso.2018.02.041

• Influence of the nature and environment of manganese in Mn-BEA zeolites on NO conversion in selective catalytic reduction with ammonia

R.BARAN, L; VALENTIN, J.M. KRAFFT, T GRZYBEK, P. GLATZEL,S. DZWIGAJ

Phys. Chem. Chem. Phys. 2017, 19, 13553-13561. DOI:10.1039/C7CP02096A

• Cobalt-containing BEA zeolite for catalytic combustion of toluene

A. ROKOCINSKA, M. DROZDEK, B. DUDEK, B. GIL, P. MICHORCZYK, D. BROURI, S. DZWIGAJ, P. KUSTROWSKI

Appl. Catal. B 2017, 212, 59-67. DOI:10.1016/j.apcatb.2017.04.067

• Ethylene production via catalytic dehydration of diluted bioethanol: A step towards an integrated biorefinery

I. ROSSETTI, M. COMPAGNONI, E. FINOCCHIO, G. RAMIS, A. DI MICHELE, Y. MILLOT, S.  DZWIGAJ

Appl. Catal. B 2017, 210, 407-420. DOI:10.1016/j.apcatb.2017.04.007

• Ethylene production from diluted bioethanol solutions

I. ROSSETTI, M. COMPAGNONI, G. DE GUIDO, L.A. PELLEGRINI, G. RAMIS, S. DZWIGAJ

Can. J. Chem. Eng.  2017, 95, 1752-1759. DOI:10.1002/cjce.22828

• Incorporation of vanadium into the framework of hydroxyapatites: importance of the vanadium content and pH conditions during the precipitation step

S. PETIT, T. GODE, C. THOMAS, S. DZWIGAJ, Y. MILLOT, D. BROURI, J.M. KRAFFT, G. ROUSSE, C. LABERTY-ROBERT, G. COSTENTIN

Phys. Chem. Chem. Phys.  2017, 19, 9630-9640. DOI:10.1039/C6CP08782E

• The impact of the hydrodechlorination process on the physicovhemical properties of bimetallic Ag-CuBeta zeolite catalysts

A. SREBOWATA, I.I. KAMINSKA, S. CASALE, D. BROURI, C. CALERS, S. DZWIGAJ

Micropor. Mesopor. Mater. 2017, 243, 56-64. DOI:10.1016/j.micromeso.2016.12.022

• Ethanol conversion into 1,3-Butadiene by Lebedev method over MTaSiBEA zeolites (M = Ag, Cu, Zn)

P. KYRIIENKO, O. LARINA, S. SOLOVIEV, S. ORLYK, C. CALERS, S. DZWIGAJ

ACS Sustainable Chemistry & Engineering, 2017, 5, 2075-2083. DOI:10.1021/acssuschemeng.6b01728

• Identification of the siver state in the framework of Ag-containing zeolite by XRD, FTIR, photoluminescence, ¹⁰⁹Ag NMR, EPR, DR UV-vis, TEM and XPS investigations

P. NATALIIA, P. KYRIIENKO, S. SOLOVIEV, R. BARAN, Y. MILLOT, S. DZWIGAJ

Phys. Chem. Chem. Phys. 2016, 18, 29458-29465. DOI:10.1039/C6CP05263K

• Influence of preparation procedure on catalytic activity of PdBEA zeolites in aqueous phase hydrodechlorination of 1,1,2-trichloroethene

I.I. KAMINSKA, D.LISOVYTSKIY, S. CASALE, A. SREBOWATA, S. DZWIGAJ

Micropor. Mesopor. Mater. 2017, 237, 65-73. DOI:10.1016/j.micromeso.2016.09.023

• Syngas production via steam reforming of biorthanol over Ni-BEA catalysts: A BTL strategy

I. ROSSETTI, M. COMPAGNONI, E. FINOCCHIO, G. RAMIS, A. DE MICHELE, A. ZUCCHINI, S. DZWIGAJ

Inter. J. Hydrogen Energy, 2016, 41, 16878-16889. DOI:10.1016/j.ijhydene.2016.07.149

• Effect of the niobium state on the properties of NbSiBEA as bifunctional catalysts for gas- and liquid-phase tandem processes

P. I. KYRIIENKO, O.V. LARINA, N.O. POPOVYCH, S.O. SOLOVIEV, Y. MILLOT, S. DZWIGAJ

J. Mol. Catal. A 2016, 424, 27-36. DOI:10.1016/j.molcata.2016.06.024

• Influence of the postsynthesis preparation procedure on catalytic behaviour of Ag-  loaded BEA zeolites in the hydrodechlorination of 1,2-dichloroethane into value added products

A. SREBOWATA, R. BARAN, G. SLOWIK, D. LISOVYTSKIY, S. DZWIGAJ

Appl. Catal. B 2016, 199, 514-522. DOI:10.1016/j.apcatb.2016.06.060

Diplômes français et étrangers

• Habilitation à diriger des recherches,  2004
• Thèse de Doctorat à l’nstitut de Catalyse et de Chimie de Surface, Académie des Sciences de Pologne, Cracovie, Pologne,  1982
• Maîtrise de Chimie à l’Institut de Chimie, Université Technique, Cracovie, Pologne, 1978